Self-assembly between dicarboxylate ions and a binuclear europium complex: formation of stable adducts and heterometallic lanthanide complexes.
نویسندگان
چکیده
A binuclear lanthanide complex consisting of two lanthanide binding domains linked by a m-xylyl bridging unit forms very stable 1 : 1 adducts with benzene dicarboxylic acids and their derivatives. The complex with isophthalate derivatives is particularly stable.
منابع مشابه
Thermodynamics of Self-Assembly of Dicarboxylate Ions with Binuclear Lanthanide Complexes
Self-assembly of a range of carboxylic acids (benzoic acid, dinicotinic acid, nicotinic acid, and isophthalic acid) with the europium complex of 5-nitro-α,α'-bis(DO3Ayl)-m-xylene (where DO3A is 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid) has been explored to establish the thermodynamics of binding in a range of solvent systems and in a range of aqueous buffer solutions. In this system,...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 45 شماره
صفحات -
تاریخ انتشار 2011